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Hydrochloric Acid → Ammonium trifluoromethanesulfonate

HRID 537718
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 537718
C1([Si](OC)(OC)OC)C=CC=CC=1.C(O[Si](OCC)(OCC)OCC)C.C[Si](OCC)(OCC)OCC.[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].CO[Si](CCC[N+:56](C)(C)C)(OC)OC.Cl.C(OCC(O)C)C>O.CC(C)=O.CO.C(O)C>[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].[NH4+:56]
KomponentenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

11

Edukt 6

HCID 313Hydrochloric Acid2×HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 86654381Trimethoxysilylpropyltrimethylammonium trifluoromethanesulfonate

Produkt 1

HCID 15842047
Ammonium trifluoromethanesulfonate

Reagenzien, Katalysatoren, Lösungsmittel 4

HCID 180AcetoneLösungsmittel2×HCID 702EthanolLösungsmittelHCID 887MethanolLösungsmittel2×HCID 962WaterLösungsmittel

Versuchsvorschrift

4.92 g of phenyltrimethoxysilane, 72.42 g of tetraethoxysilane, 22.05 g of methyltriethoxysilane, 0.61 g of the 30% methanol solution of trimethoxysilylpropyltrimethylammonium trifluoromethanesulfonate, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.11 g of 0.01 M hydrochloric acid was added to the mixed solution. The mixed solution was subjected to the reaction for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol and methanol as reaction by-products, acetone, water, and hydrochloric acid were distilled off under reduced pressure to obtain a hydrolysis-condensation product. The polymer thus obtained corresponded to Formula (VII-30):

Aufarbeitung

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customThe mixed solution was subjected to the reaction for 240 minutes
  6. customthe resultant reaction solution
  7. distillationwere distilled off under reduced pressure
  8. customto obtain a hydrolysis-condensation product
  9. customThe polymer thus obtained

Quellen und Nachweise

ORD-Eintrag
ord-ce4b5603365f4492aa4085411388b524
Quelldatensatz
uspto-grants-2014_10
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US08864894B2

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