4-Phenyl-2-butanol → 4-Methoxybenzyl alcohol

HRID 541177

Reaktionsgleichung

Reaktionsgleichung von HRID 541177
O[CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6]N=1)[CH3:3].C1(CC[CH:18]([OH:20])C)C=CC=CC=1.C1C2C3[NH+]([O-:30])C(C2)CC1C3>>[CH3:18][O:20][C:4]1[CH:9]=[CH:8][C:7]([CH2:6][OH:30])=[CH:3][CH:2]=1

Komponenten

4

Edukt 3

HCID 613024-Phenyl-2-butanolHCID 86784alpha-Methyl-2-pyridinemethanolHCID 1015366402-Oxido-2-azoniatricyclo[3.3.1.03,7]nonane

Produkt 1

HCID 77384-Methoxybenzyl alcohol

Versuchsvorschrift

2-(1-Hydroxyethyl)pyridine (76.8 mg, 0.624 mmol) was oxidized in the same manner as that described in Example 8, (a) (except that Nor-AZADO was used at 3 mol %, and the reaction was performed at room temperature) to obtain the objective compound (66.0 mg; yield, 87.4%). The spectrum data were found to be the same as those obtained in Example 6, (h).

Aufarbeitung

  1. customwas performed at room temperature
  2. customto obtain
  3. customthe objective compound (66.0 mg; yield, 87.4%)

Quellen und Nachweise

ORD-Eintrag
ord-31220d8df9174332927d5f16647c901d
Quelldatensatz
uspto-grants-2014_10
Patentnummer
US08871981B2

Verknüpfte Notizen

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