Dicyclohexylamine → 2-Propenamide, N,N-dicyclohexyl-

HRID 5492

Reaktionsgleichung

Reaktionsgleichung von HRID 5492
[CH:1]1([NH:7][CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C(N(CC)CC)C.[C:21](Cl)(=[O:24])[CH:22]=[CH2:23]>C(OCC)C>[CH:8]1([N:7]([CH:1]2[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]2)[C:21](=[O:24])[CH:22]=[CH2:23])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]1

Komponenten

5

Edukt 3

HCID 7582DicyclohexylamineHCID 8471TriethylamineHCID 13140Acryloyl chloride

Produkt 1

HCID 101054982-Propenamide, N,N-dicyclohexyl-

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel2×

Versuchsvorschrift

A solution of dicyclohexylamine (19.92 ml, 0.10 mole) and triethylamine (27.88 ml, 0.20 mole) in ethyl ether (100 ml) was cooled to 0° C. A solution of acryloyl chloride (7.93 ml, 0.1 mole) in ethyl ether (20 ml) was added and the solution was stirred for 12 hours, filtered and concentrated to obtain the product as a solid which was dried in vacuo. The structure was confirmed by NMR.

Aufarbeitung

  1. filtrationfiltered
  2. concentrationconcentrated

Quellen und Nachweise

ORD-Eintrag
ord-1a30f638e6c14bbab25c98517e050aa1
Quelldatensatz
uspto-grants-1993_09
Patentnummer
US05244899

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