Morpholine → 3-Amino-3-morpholinoacrylonitrile

HRID 565439Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 565439
[C:1]([CH2:3][C:4](=[NH:8])OCC)#[N:2].[NH:9]1[CH2:14][CH2:13][O:12][CH2:11][CH2:10]1>C(O)C>[NH2:8][C:4]([N:9]1[CH2:14][CH2:13][O:12][CH2:11][CH2:10]1)=[CH:3][C:1]#[N:2]

Komponenten

4

Edukt 2

HCID 8083MorpholineHCID 256188Ethyl 2-cyanoethanecarboximidate

Produkt 1

HCID 27636313-Amino-3-morpholinoacrylonitrile

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

In anhydrous ethanol (10 ml) was dissolved ethyl 2-cyanoacetimidate (1.0 g), followed by addition of morpholine (0.78 g). The mixture was stirred at room temperature for 4 hours, and the separated crystals were collected by filtration. This crystal crop was used as it was in the next reaction.

Aufarbeitung

  1. filtrationthe separated crystals were collected by filtration
  2. customwas in the next reaction

Quellen und Nachweise

ORD-Eintrag
ord-fd12486b577e4589a54a67f04c396b41
Quelldatensatz
uspto-grants-2001_01
Patentnummer
US06172102B2

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