Trichloromethanethiol → bis(4-Fluorophenyl)methyl(5-trichloromethylthio-1H-1,2,4-triazol-1-ylmethyl)silane

HRID 568777

Reaktionsgleichung

Reaktionsgleichung von HRID 568777
[F:1][C:2]1[CH:7]=[CH:6][C:5]([Si:8]([C:16]2[CH:21]=[CH:20][C:19]([F:22])=[CH:18][CH:17]=2)([CH3:15])[CH2:9][N:10]2[CH:14]=[N:13][CH:12]=[N:11]2)=[CH:4][CH:3]=1.C(N(CC)CC)C.[Cl:30][C:31]([SH:34])([Cl:33])[Cl:32]>C(Cl)Cl>[F:1][C:2]1[CH:3]=[CH:4][C:5]([Si:8]([C:16]2[CH:17]=[CH:18][C:19]([F:22])=[CH:20][CH:21]=2)([CH3:15])[CH2:9][N:10]2[C:14]([S:34][C:31]([Cl:33])([Cl:32])[Cl:30])=[N:13][CH:12]=[N:11]2)=[CH:6][CH:7]=1

Komponenten

5

Edukt 3

HCID 6390TrichloromethanethiolHCID 8471TriethylamineHCID 73675Flusilazole

Produkt 1

HCID 20149076bis(4-Fluorophenyl)methyl(5-trichloromethylthio-1H-1,2,4-triazol-1-ylmethyl)silaneAusbeute 59,6 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel2×

Versuchsvorschrift

To a solution of 4.0 g (0.013 mol) of bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane and 2.0 mL (0.014 mol) of triethylamine in 50 mL of methylene chloride at 6° was added 1.4 mL (0.013 mol) of perchloromethylmercaptan over 2 minutes. The reaction temperature rose 6°. The dark solution was stirred at 25° for 2 hours, then diluted with methylene chloride, washed with water and brine, and evaporated to give 3.6 g of the title compound as an oil: ir (neat) 3100, 3020, 2960, 1590, 1500; nmr (CDCl3) δ 0.7 (3H, s), 4.4 (2H, s), 7.1 (4H, t), 7.5 (4H, dd), 8.1 (1H, s); mass spectrum: m/e 464.

Aufarbeitung

  1. customrose 6°
  2. washwashed with water and brine
  3. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-cb5aab9be2b642e4b7534e1a0363d5fd
Quelldatensatz
uspto-grants-1988_03
Patentnummer
US04729986

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