HCID 59379802, Verbindung → HCID 59379814, Verbindung

HRID 598748Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 598748
[CH3:1][O:2][C:3](=[O:25])[C:4]([C:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9]([O:16][CH2:17][CH2:18][N:19]2[CH2:24][CH2:23][O:22][CH2:21][CH2:20]2)=[CH:8][CH:7]=1)=[O:5]>CO.[Pd]>[CH3:1][O:2][C:3](=[O:25])[CH:4]([OH:5])[C:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9]([O:16][CH2:17][CH2:18][N:19]2[CH2:20][CH2:21][O:22][CH2:23][CH2:24]2)=[CH:8][CH:7]=1

Komponenten

4

Edukt 1

HCID 59379802HCID 59379802, Verbindung

Produkt 1

HCID 59379814HCID 59379814, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 887MethanolLösungsmittelHCID 23938PalladiumLösungsmittel

Versuchsvorschrift

To a solution of 12 (1 g, 2.9 mmol) in MeOH (10 mL), Pd/C (10 wt %) was added and the mixture stirred at rt under H2 atmosphere. Upon completion of the reaction (monitored by LCMS), the mixture was filtered through celite and the filtrate evaporated to give a yellow oil which solidified upon standing. Calculated mass=345. Observed mass=345.

Aufarbeitung

  1. customUpon completion of the reaction (monitored by LCMS)
  2. filtrationthe mixture was filtered through celite
  3. customthe filtrate evaporated
  4. customto give a yellow oil which

Quellen und Nachweise

ORD-Eintrag
ord-4a4637a108dd4243855c9e7ec6d2251d
Quelldatensatz
uspto-grants-2011_03
Patentnummer
US07897599B2

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