Water → HCID 67040477, Verbindung

HRID 605311Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 605311
[CH2:1]([O:3][C:4]([C:6]1[S:7][C:8](Cl)=[C:9]([N+:11]([O-:13])=[O:12])[CH:10]=1)=[O:5])[CH3:2].[SH:15][C:16]1[CH:21]=[CH:20][C:19]([OH:22])=[CH:18][CH:17]=1.C(=O)([O-])[O-].[Cs+].[Cs+].O>CN(C)C=O>[CH2:1]([O:3][C:4]([C:6]1[S:7][C:8]([S:15][C:16]2[CH:21]=[CH:20][C:19]([OH:22])=[CH:18][CH:17]=2)=[C:9]([N+:11]([O-:13])=[O:12])[CH:10]=1)=[O:5])[CH3:2]

Komponenten

6

Edukt 4

HCID 962WaterHCID 10796Cesium carbonateHCID 2401474-MercaptophenolHCID 56763846HCID 56763846, Verbindung

Produkt 1

HCID 67040477HCID 67040477, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

The product from Example 351A (1 equiv) and 4-mercaptophenol (1 equiv) were dissolved in dimethylformamide and cesium carbonate (5 equiv) added. The resultant mixture was stirred at 80° C. for 2.5 hours, cooled to room temperature and water added. The solution was extracted with ethyl acetate, the organic extracts dried and concentrated under vacuum to provide the title product.

Aufarbeitung

  1. extractionThe solution was extracted with ethyl acetate
  2. customthe organic extracts dried
  3. concentrationconcentrated under vacuum

Quellen und Nachweise

ORD-Eintrag
ord-149745779bac4c5f9a7501b9b1308c5e
Quelldatensatz
uspto-grants-2011_03
Patentnummer
US07910595B2

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