Oxygen → 2-Pinanol

HRID 618991

Reaktionsgleichung

Reaktionsgleichung von HRID 618991
[CH:1]12[CH2:9][CH:5]([C:6]1([CH3:8])[CH3:7])[CH2:4][CH2:3][CH:2]2[CH3:10].[OH:11]N1C(=O)C2=CC=CC=C2C1=O.O=O>C(#N)C>[CH:1]12[CH2:9][CH:5]([C:6]1([CH3:8])[CH3:7])[CH2:4][CH2:3][C:2]2([OH:11])[CH3:10]

Komponenten

5

Edukt 3

HCID 977OxygenHCID 10129Pinane2×HCID 10665N-Hydroxyphthalimide

Produkt 1

HCID 101282-PinanolAusbeute 82 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

To 25 milliliters of acetonitrile were added 1.38 grams (10 millimoles) of pinane, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide and 0.015 gram (0.06 millimole) of Co(AA)2, and the resultant mixture was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. Pinane was transformed into 2-pinanol (selectivity for pinane 91%, yield 82%) with a transformation rate of 90%.

Quellen und Nachweise

ORD-Eintrag
ord-2d1f307dec764a8ead7ab279d21b9f11
Quelldatensatz
uspto-grants-1999_09
Patentnummer
US05958821

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