HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1,2-Epoxydodecane → 1-[4-(1,1-Dioxo-thiomorpholin-4-yl)-phenoxy]-3-(nonyl)propan-2-ol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1,2-Epoxydodecane | HCID 17858 | — |
| Edukt | 4-(4-Hydroxyphenyl)thiomorpholine 1,1-Dioxide | HCID 21845223 | — |
| Katalysator | Phosphonium, ethyltriphenyl-, bromide (1:1) | HCID 73727 | — |
| Produkt | 1-[4-(1,1-Dioxo-thiomorpholin-4-yl)-phenoxy]-3-(nonyl)propan-2-ol | HCID 21845238 | 38,9% |
Reaktionsschritte
4-(1,1-dioxo-thiomorpholin-4-yl)phenol (2.3 g, 10 mmol), 2-(decyl)-oxirane (1.9 g, 10 mmol) and ethyltriphenylphosphonium bromide (0.2 g) are reacted and purified as described for compound 102 to afford a light browm solid 1.6 g (38%), m.p. 84° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05958663 |
| Quelldatensatz | uspto-grants-1999_09 |
| ORD ID | ord-baab20b918d040c59e85127047e616ec |
| Quellennotiz | uspto-grants-1999_09 |