HRID619099

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID17858

1,2-Epoxydodecane

C12H24O

HCID21845223

4-(4-Hydroxyphenyl)-1lambda~6~,4-thiazinane-1,1-dione

C10H13NO3S

PRODUCTS

生成物

结构：CCCCCCCCCCC(O)COc1ccc(N2CCS(=O)(=O)CC2)cc1

HCID21845238

未命名化合物

收率 38.9%

AUXILIARIES

试剂、催化剂与溶剂

结构：CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

催化剂HCID73727

Phosphonium, ethyltriphenyl-, bromide (1:1)

C20H20BrP

PROCEDURE

实验过程

4-(1,1-dioxo-thiomorpholin-4-yl)phenol (2.3 g, 10 mmol), 2-(decyl)-oxirane (1.9 g, 10 mmol) and ethyltriphenylphosphonium bromide (0.2 g) are reacted and purified as described for compound 102 to afford a light browm solid 1.6 g (38%), m.p. 84° C.

WORKUP

后处理

custompurified