Hydrochloric Acid → 4-Methyl-1-naphthol

HRID 619872

Reaktionsgleichung

Reaktionsgleichung von HRID 619872
[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([O:12]C)=[CH:4][CH:3]=1.Cl.N1C=CC=CC=1.Cl>>[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([OH:12])=[CH:4][CH:3]=1

Komponenten

4

Edukt 3

HCID 313Hydrochloric AcidHCID 43814674-Methoxy-1-methylnaphthaleneHCID 10176127Pyridinium chloride

Produkt 1

HCID 824834-Methyl-1-naphthol

Reaktionsbedingungen

Temperatur
200 °C

Versuchsvorschrift

4-Methyl-1-methoxynaphthalene (4) (145 g) was mixed with pyridine hydrochloride (250 g) and the mixture was heated at 200° C. for 3 hours. The mixture was cooled, treated with dilute hydrochloric acid, and extracted with ether. The ether extract was dried (MgSO4), filtered and the solvent removed, leaving a black oil which was extracted with petroleum b.p. 60°-80° C. (4×100 cm3). 4-Methyl-1-naphthol (5) was obtained as near colourless oily crystals which darken on storage.

Aufarbeitung

  1. temperatureThe mixture was cooled
  2. extractionextracted with ether
  3. extractionThe ether extract
  4. dry with materialwas dried (MgSO4)
  5. filtrationfiltered
  6. customthe solvent removed
  7. customleaving a black oil which
  8. extractionwas extracted with petroleum b.p. 60°-80° C. (4×100 cm3)

Quellen und Nachweise

ORD-Eintrag
ord-f30e9ede785445388d3e53904cba5691
Quelldatensatz
uspto-grants-1989_04
Patentnummer
US04818096

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