4-Methoxyphenol → 4-Methoxycyclohexanol (cis,trans)

HRID 633520

Reaktionsgleichung

Reaktionsgleichung von HRID 633520
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1>C(O)(=O)C.[Pt]=O>[CH3:1][O:2][CH:3]1[CH2:8][CH2:7][CH:6]([OH:9])[CH2:5][CH2:4]1

Komponenten

4

Edukt 1

HCID 90154-Methoxyphenol

Produkt 1

HCID 1403324-Methoxycyclohexanol (cis,trans)

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 82844Platinum oxide (PtO)KatalysatorHCID 176Acetic AcidLösungsmittel

Reaktionsbedingungen

Temperatur
50 °C

Versuchsvorschrift

A mixture of 4-methoxyphenol (0.10 g, 0.806 mmol) in acetic acid (10 mL) was added to platinum oxide (0.020 g, 0.088 mmol) in a 50 mL pressure bottle and heated at 50° C. under hydrogen at 30 psi for 1 hour. The solid was removed by filtration, and the filtrate was concentrated to provide the title compound.

Aufarbeitung

  1. customThe solid was removed by filtration
  2. concentrationthe filtrate was concentrated

Quellen und Nachweise

ORD-Eintrag
ord-2dc8bd4942754b03ab5ddc5dbd1b51dd
Quelldatensatz
uspto-grants-2016_04
Patentnummer
US09321764B2

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