3-(Chlorocarbonyl)phenyl acetate → N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine

HRID 637256

Reaktionsgleichung

Reaktionsgleichung von HRID 637256
[C:1]([O:4][C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][CH:13]=1)[C:8](Cl)=[O:9])(=[O:3])[CH3:2].[K].[CH3:15][S:16]([CH3:19])(=[NH:18])=[O:17]>O1CCCC1>[C:1]([O:4][C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][CH:13]=1)[C:8]([N:18]=[S:16]([CH3:19])([CH3:15])=[O:17])=[O:9])(=[O:3])[CH3:2]

Komponenten

4

Edukt 2

HCID 129985583-(Chlorocarbonyl)phenyl acetateHCID 86740516Dimethyl sulphoximine potassium salt

Produkt 1

HCID 20256530N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Reaktionsbedingungen

Temperatur
-35 °C

Versuchsvorschrift

A solution of 99.3 g of m-acetoxybenzoyl chloride in 150 ml of absolute tetrahydrofuran is added dropwise at -35° C. during 20 minutes while stirring to the dimethyl sulphoximine potassium salt suspension and the mixture is then stirred at -35° C. for 30 minutes. N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine is thus formed in suspension.

Quellen und Nachweise

ORD-Eintrag
ord-7abe3c7ad9e0455ab3840a266774c0b4
Quelldatensatz
uspto-grants-1985_12
Patentnummer
US04556413

Verknüpfte Notizen

Wird geladen…