Morpholine → HCID 13654956, Verbindung

HRID 648911Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 648911
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[I-:7].C[C:9]1[S:13][CH:12]=[CH:11][S+:10]=1>C(O)C>[I-:7].[S:10]1[CH:11]=[CH:12][S:13][C:9]1=[N+:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1

Komponenten

4

Edukt 2

HCID 8083MorpholineHCID 20144152HCID 20144152, Verbindung

Produkt 1

HCID 13654956HCID 13654956, VerbindungAusbeute 79,7 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

1.0 g of morpholine and 2.8 g of 2-methyl-1,3-dithiolium iodide were treated in the same manner as in Example 26, and the product was recrystallized from ethanol, whereby 2.4 g (yield: 79.7%) of 4-(1,3-dithiol-2-ylidene)morpholinium iodide (Compound No. 29) was obtained as crystals having a melting point of from 257° to 258° C.

Quellen und Nachweise

ORD-Eintrag
ord-eceda90404af4bb0aa3cebb0efdc7b4b
Quelldatensatz
uspto-grants-1988_04
Patentnummer
US04737494

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