Tetrafluoro-m-phenylenediamine dihydrochloride → HCID 86757235, Verbindung

HRID 650127Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 650127
[Br-:1].[CH2:2]([N+:5]1([CH2:10][CH:11]=[CH2:12])[CH2:9][CH2:8][CH2:7][CH2:6]1)[CH:3]=[CH2:4].[Cl-:13].[CH2:14]([NH2+:17][CH2:18][CH:19]=[CH2:20])[CH:15]=[CH2:16].C1(N)C(F)=C(F)C(F)=C(N)C=1F.Cl.Cl>O>[Br-:1].[CH2:10]([N+:5]1([CH2:2][CH:3]=[CH2:4])[CH2:9][CH2:8][CH2:7][CH2:6]1)[CH:11]=[CH2:12].[Cl-:13].[CH2:14]([NH2+:17][CH2:18][CH:19]=[CH2:20])[CH:15]=[CH2:16]

Komponenten

5

Edukt 3

HCID 149026Tetrafluoro-m-phenylenediamine dihydrochlorideHCID 10898762Diallylamine hydrochlorideHCID 15812374HCID 15812374, Verbindung

Produkt 1

HCID 86757235HCID 86757235, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
70 °C

Versuchsvorschrift

23.22 9 of N,N-diallylpyrrolidinium bromide (EXAMPLE 1) and 3.34 g of diallylarnmonium chloride (EXAMPLE 7) were dissolved in 26.5 g of deionized water to make a 50% solution of the monomer. To the monomer solution was added 1.6 g of 2,2′-azobis(2-am-indinopropane) dihydrochloride and the reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes. While stirring the temperature was raised to 70° C. for 48 hours. After cooling to room temperature, 55 g of viscous polymer solution was obtained.

Aufarbeitung

  1. customthe reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes
  2. temperatureAfter cooling to room temperature

Quellen und Nachweise

ORD-Eintrag
ord-2bdbf6e39fcb46d8a93664802580ad67
Quelldatensatz
uspto-grants-2001_08
Patentnummer
US06271264B1

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