Benzoyl chloride → Allyl benzoate

HRID 65133

Reaktionsgleichung

C(Cl)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10](=[O:19])([O:15][CH2:16][CH:17]=[CH2:18])OCC=C>[Cl-].[Zn+2].[Cl-]>[C:10]([O:15][CH2:16][CH:17]=[CH2:18])(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Komponenten

Reaktionsbedingungen

Temperatur: 60 °C

Versuchsvorschrift

In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.

Aufarbeitung

customreacinitiated at room temperature
temperatureheating at 80° C. for an additional 3 hours
distillationDistillation

Quellen und Nachweise

ORD-Eintrag: ord-39ac0fe3490b4b4ca1802b534a76f6ac
Quelldatensatz: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04612386

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