N-Phenylanthranilic Acid → N-phenylanthranilic acid cobalt
Reaktionsgleichung
C([O-])(=O)C.[Co+2:5].C([O-])(=O)C.[C:10]1([NH:16][C:17]2[C:18](=[CH:22][CH:23]=[CH:24][CH:25]=2)[C:19]([OH:21])=[O:20])[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>CN(C)C=O>[Co:5].[C:10]1([NH:16][C:17]2[C:18](=[CH:22][CH:23]=[CH:24][CH:25]=2)[C:19]([OH:21])=[O:20])[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 50 °C
Versuchsvorschrift
24.9 g (0.1 mol) of cobalt acetate was added to 500 ml of dimethylformamide and completely dissolved. The solution was heated to 50° C., and 42.6 g (0.2 mol) of N-phenylanthranilic acid was gradually added thereto. The mixture was allowed to react for 3 hours at about 145° C. under refluxing, and the heating was terminated. The mixture, when cooled down to 100° C., was dispersed in 2 liters of water and, after 1 hour, subjected to filtration. The precipitate was washed with water until neutrality and then dried at 90° C., whereby about 40 g of pale reddish grey powder.