Acrylamide → Sodium Persulfate

HRID 652996

Reaktionsgleichung

Reaktionsgleichung von HRID 652996
C(N)(=O)C=C.C([O-])(=O)C(CC([O-])=O)=C.[Na+:15].[Na+].[PH2]([O-])=O.[Na+].CC(OC=C)=O.C=CCl.[S:30]([O:34][O:35][S:36]([O-:39])(=[O:38])=[O:37])([O-:33])(=[O:32])=[O:31]>O.C(N(CC([O-])=O)CC([O-])=O)CN(CC([O-])=O)CC([O-])=O.[Na+].[Na+].[Na+].[Na+]>[S:30]([O:34][O:35][S:36]([O-:39])(=[O:38])=[O:37])([O-:33])(=[O:32])=[O:31].[Na+:15].[Na+:15]

Komponenten

8

Edukt 5

HCID 6579AcrylamideHCID 61927Vinyl chloride-vinyl acetateHCID 79326Butanedioic acid, 2-methylene-, sodium salt (1:2)HCID 107879Peroxydisulfate2×HCID 178527019HCID 178527019, Verbindung

Produkt 1

HCID 62655Sodium Persulfate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 6144Edetate SodiumKatalysatorHCID 962WaterLösungsmittel4×

Reaktionsbedingungen

Temperatur
75 °C

Versuchsvorschrift

Into a 1 liter resin flask fitted with a stirrer, condensor, thermometer, nitrogen inlet and port for adding liquid is placed 425 g of deionized water, 200 g of a 50% solution of acrylamide, 276 g of a 50% solution of AMPS, 30 g of a 40% solution of disodium itaconate and 0.24 g of Versene 100. The solution is stirred and to it added 0.2 g of sodium hypophosphite dissolved in 16 g of deionized water. The solution is stirred, nitrogen introduced sub-surface and the solution then heated to 75° C. by means of an external heating jacket. A solution of 2.5g of sodium persulfate in 50 g of deionized water is prepared and placed in a metering pump connected to the resin flask at the inlet port with a fine tygon tubing. The persulfate solution is added uniformly over a period of 2 hours, maintaining a temperature of 75° C.±2° C. by initially cooling and then warming. At the end of the persulfate addition, 75° C. is maintained for an additional 1 hour, the solution cooled to 40° C. and discharged. The resulting product was a clear, light green-yellow liquid with a solids content of 25%. The viscosity, as measured on a Brookfield viscometer was 7,500 cps, spindle 3, speed 12. The pH of the solution was 7 to 7.6. The molecular weight of the polymer was about 500,000 as measured by GPC. The product was completely water miscible.

Aufarbeitung

  1. customInto a 1 liter resin flask fitted with a stirrer
  2. additioncondensor, thermometer, nitrogen inlet and port for adding liquid
  3. stirringThe solution is stirred
  4. temperaturemaintaining a temperature of 75° C.±2° C.
  5. temperatureby initially cooling
  6. temperaturewarming
  7. temperatureis maintained for an additional 1 hour
  8. temperaturethe solution cooled to 40° C.

Quellen und Nachweise

ORD-Eintrag
ord-0c406b6c62cf4ef585a1a8fbb3b73ac7
Quelldatensatz
uspto-grants-1987_06
Patentnummer
US04674574

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