Ammonia → Indoaniline

HRID 653014

Reaktionsgleichung

Reaktionsgleichung von HRID 653014
[NH2:1][C:2]1[CH:3]=[CH:4][C:5](C)=[C:6](O)[CH:7]=1.[NH3:10].[OH2:11]>[Fe-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]>[CH:2]1[C:3](=[N:10][C:5]2[CH:6]=[CH:7][C:2]([NH2:1])=[CH:3][CH:4]=2)[CH:4]=[CH:5][C:6](=[O:11])[CH:7]=1

Komponenten

5

Edukt 3

HCID 222AmmoniaHCID 962WaterHCID 178185-Amino-2-methylphenol

Produkt 1

HCID 24748760Indoaniline

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 178511488HCID 178511488, VerbindungKatalysator

Versuchsvorschrift

0.02 mole (2.46 g) 5-amino 2-methyl phenol and 0.02 mole (2.85 g) chloroparaphenylene diamine are dissolved in 200 cc water to which have been added 50 cc ammonia 22° Be. To this mixture there is added, little by little with agitation, 0.04 mole (13.16 g) potassium ferricyanide. The reaction mass is then filtered on a suction filter and a yield of 5 g of said indoaniline is obtained. After recrystallization in a pyridine and water mixture, the said indoaniline recovered melts at 120°.

Aufarbeitung

  1. additionTo this mixture there is added
  2. filtrationThe reaction mass is then filtered on a suction
  3. filtrationfilter

Quellen und Nachweise

ORD-Eintrag
ord-93d9fd52876c475699384c267fd14b40
Quelldatensatz
uspto-grants-1987_06
Patentnummer
US04675130

Verknüpfte Notizen

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