38263-46-6 → HCID 55300761, Verbindung

HRID 656253Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 656253
[C@H:1]12[O:7][C@H:4]([CH:5]=[CH:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]>C(O)C.[Pd]>[C@H:1]12[O:7][C@@H:4]([CH2:5][CH2:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]

Komponenten

4

Edukt 1

HCID 983398038263-46-6

Produkt 1

HCID 55300761HCID 55300761, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

A solution of 1 mmol of (1S,2R,4S)-7-oxabicyclo[2.2.1]-hept-5-ene-2-carboxylic acid [185840-15-7] in 30 ml of ethanol is hydrogenated in the presence of 0.150 g of Pd/C 10% at room temperature until conversion is complete. The reaction mixture is clarified by filtration, and the filtrate is evaporated. The title compound is obtained from the residue by flash chromatography (SiO2 60 F).

Aufarbeitung

  1. filtrationThe reaction mixture is clarified by filtration
  2. customthe filtrate is evaporated

Quellen und Nachweise

ORD-Eintrag
ord-04eaa553a8774abab23d4618f0b453fb
Quelldatensatz
uspto-grants-2011_12
Patentnummer
US08071651B2

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