Reaktionsgleichung
[CH:1](CC[Si](Cl)(Cl)Cl)=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.Cl[SiH](C)C.[CH3:19][CH2:20]CCCC>[Pt]>[CH:19]([C:6]1[CH:5]=[CH:4][C:3]([CH:2]=[CH2:1])=[CH:8][CH:7]=1)=[CH2:20]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
(Styrylethyl)-trichlorosilane is first synthesized by a platinum-catalyzed mono-hydrosilylation of p-DVB with chlorodimethylsilane in hexane. Kim, I-J.; Faust, R. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem) 2000, 41(2), 1309. A styryl-POSS macromer is then prepared by corner capping reaction of incompletely condensed trisilanol (c-C5H9)7Si7O9(OH)3 with (styrylethyl)-trichlorosilane, according to the procedure reported in Haddad, T. S.; Lichtenhan, J. D. Macromolecules 1996, 29, 7302.
Quellen und Nachweise
- ORD-Eintrag
- ord-8f775f514068446bbda78c8538229c68
- Quelldatensatz
- uspto-grants-2011_12
- Patentnummer
- US08075906B2
Verknüpfte Notizen
Wird geladen…