HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(R)-(+)-1,1,1-trifluoro-2-octyl 4-benzyloxybenzoate → 4-hydroxybenzoic acid (R)-1-trifluoromethyl-heptyl ester
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (R)-(+)-1,1,1-trifluoro-2-octyl 4-benzyloxybenzoate | HCID 22850730 | — |
| Lösungsmittel | Ethyl Acetate | HCID 8857 | — |
| Produkt | 4-hydroxybenzoic acid (R)-1-trifluoromethyl-heptyl ester | HCID 14549217 | 99% |
Reaktionsschritte
2.2 g of [R]-1-trifluoromethylheptyl 4-benzyloxybenzoate, (13) 100 mg of PdOH/C in 50 ml of ethyl acetate was stirred at RT over night under H2 atmosphere. Then the catalyst was filtered out and filtrate was evaporated to dryness to give the pure compound in yield of 99%.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07083832B2 |
| Quelldatensatz | uspto-grants-2006_08 |
| ORD ID | ord-3687b0a5c976428fb52ff00b4203cdb7 |
| Quellennotiz | uspto-grants-2006_08 |