Sodium sulfide nonahydrate → 3,3'-[(5-Amino-1,3-phenylene)bis(carbonylimino)]bis[2,7-naphthalenedisulfonic acid] tetrasodium salt

HRID 65904

Reaktionsgleichung

Reaktionsgleichung von HRID 65904
[Na+:1].[Na+].[Na+].[Na+].[N+:5]([C:8]1[CH:9]=[C:10]([C:35]([NH:37][C:38]2[C:39]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:40][C:41]3[C:46]([CH:47]=2)=[CH:45][CH:44]=[C:43]([S:48]([O-:51])(=[O:50])=[O:49])[CH:42]=3)=[O:36])[CH:11]=[C:12]([C:14]([NH:16][C:17]2[C:18]([S:31]([O-:34])(=[O:33])=[O:32])=[CH:19][C:20]3[C:25]([CH:26]=2)=[CH:24][CH:23]=[C:22]([S:27]([O-:30])(=[O:29])=[O:28])[CH:21]=3)=[O:15])[CH:13]=1)([O-])=O.O.O.O.O.O.O.O.O.O.[S-2].[Na+].[Na+]>O>[Na+:1].[Na+:1].[Na+:1].[Na+:1].[NH2:5][C:8]1[CH:9]=[C:10]([C:35]([NH:37][C:38]2[C:39]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:40][C:41]3[C:46]([CH:47]=2)=[CH:45][CH:44]=[C:43]([S:48]([O-:51])(=[O:49])=[O:50])[CH:42]=3)=[O:36])[CH:11]=[C:12]([C:14]([NH:16][C:17]2[C:18]([S:31]([O-:34])(=[O:33])=[O:32])=[CH:19][C:20]3[C:25]([CH:26]=2)=[CH:24][CH:23]=[C:22]([S:27]([O-:30])(=[O:29])=[O:28])[CH:21]=3)=[O:15])[CH:13]=1

Komponenten

4

Edukt 2

HCID 73972Sodium sulfide nonahydrateHCID 1317113623,3'-[(5-Nitro-1,3-phenylene)bis(carbonylimino)]bis[2,7-naphthalenedisulfonic acid] tetrasodium salt

Produkt 1

HCID 1317113633,3'-[(5-Amino-1,3-phenylene)bis(carbonylimino)]bis[2,7-naphthalenedisulfonic acid] tetrasodium salt

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Reaktionsbedingungen

Temperatur
57 °C

Versuchsvorschrift

A mixture of 4.35 g of 3,3'-[(5-nitro-1,3-phenylene)bis(carbonylimino)]bis[2,7-naphthalenedisulfonic acid] tetrasodium salt in 100 ml of water is heated to 57° C. A 2.07 g portion of sodium sulfide nonahydrate is added and the reaction is allowed to cool. The reaction is reheated to 67° C. and allowed to cool. The mixture is filtered and the filtrate is acidified to pH 4 using acetic acid. The mixture is heated and then filtered with added diatomaceous earth. Upon cooling the filtrate yields a solid which is filtered, washed with 50% ethanol, absolute ethanol and finally with ether giving 3,3'-[(5-amino-1,3-phenylene)bis(carbonylimino)]bis[2,7-naphthalenedisulfonic acid] tetrasodium salt.

Aufarbeitung

  1. temperatureto cool
  2. customis reheated to 67° C.
  3. temperatureto cool
  4. filtrationThe mixture is filtered
  5. temperatureThe mixture is heated
  6. filtrationfiltered
  7. additionwith added diatomaceous earth
  8. temperatureUpon cooling the filtrate
  9. customyields a solid which
  10. filtrationis filtered
  11. washwashed with 50% ethanol, absolute ethanol and finally with ether

Quellen und Nachweise

ORD-Eintrag
ord-e754c26c1f46414b8485018f79cb3733
Quelldatensatz
uspto-grants-1978_12
Patentnummer
US04129591

Verknüpfte Notizen

Wird geladen…