Pyridine → Butyl 7-(tert-butylperoxy)-3,7-dimethyloctyl carbonate

HRID 65978

Reaktionsgleichung

Reaktionsgleichung von HRID 65978
[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][C:9]([CH3:17])([O:11][O:12][C:13]([CH3:16])([CH3:15])[CH3:14])[CH3:10])[CH2:3][CH2:4][OH:5].N1C=CC=CC=1.Cl[C:25]([O:27][CH2:28][CH2:29][CH2:30][CH3:31])=[O:26]>C(OCC)C>[C:25](=[O:26])([O:27][CH2:28][CH2:29][CH2:30][CH3:31])[O:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][CH2:7][CH2:8][C:9]([CH3:17])([O:11][O:12][C:13]([CH3:16])([CH3:15])[CH3:14])[CH3:10]

Komponenten

5

Edukt 3

HCID 1049PyridineHCID 61140Butyl chloroformateHCID 536641833,7-Dimethyl-7-(t-butylperoxy)octyl alcohol

Produkt 1

HCID 23346617Butyl 7-(tert-butylperoxy)-3,7-dimethyloctyl carbonate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel2×

Versuchsvorschrift

To a solution of 7.9 g (0.03 mole) of 3,7-dimethyl-7(t-butylperoxy)octyl alcohol and 2.4 g (0.03 mole) of pyridine in diethyl ether cooled at 10°±1° C was added a solution of 4.09 (0.03 mole) of n-butyl chloroformate in diethyl ether. The reaction temperature was maintained at 15°±1° C during the addition.

Aufarbeitung

  1. temperatureThe reaction temperature was maintained at 15°±1° C during the addition

Quellen und Nachweise

ORD-Eintrag
ord-22cf3ce5ef674b899ba6e662b054e132
Quelldatensatz
uspto-grants-1978_12
Patentnummer
US04129700

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