Water → 2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)-

HRID 68019

Reaktionsgleichung

Reaktionsgleichung von HRID 68019
O[C:2]1([CH3:11])[CH:6]([CH2:7][CH:8]=[CH2:9])[C:5](=[O:10])[CH:4]=[CH:3]1.[Cl-].[Na+].[OH2:14]>>[CH2:7]([C:6]1[C:5](=[O:10])[CH2:4][CH:3]([OH:14])[C:2]=1[CH3:11])[CH:8]=[CH2:9]

Komponenten

4

Edukt 3

HCID 962WaterHCID 5234Sodium ChlorideHCID 128798724-Hydroxy-4-methyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one

Produkt 1

HCID 110832-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)-

Versuchsvorschrift

In an autoclave, 4-hydroxy-4-methyl-5-allyl-2-cyclopentenone (20 g) and water (400 ml) were charged, and the resultant mixture was stirred at 180° C. for 6 hours in a nitrogen atmosphere. After cooling, sodium chloride (50 g) was added to the reaction mixture, and the resulting mixture was extracted with methyl isobutyl ketone. The extract was concentrated under reduced pressure to give 2-allyl-3-methyl-4-hydroxy-2-cyclopentenone (19 g). Yield, 95%. M.P. 130°-132° C./1.2 mmHg.

Aufarbeitung

  1. temperatureAfter cooling
  2. extractionthe resulting mixture was extracted with methyl isobutyl ketone
  3. concentrationThe extract was concentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-8371605ffe1349dc8bb6c0fe1adc2020
Quelldatensatz
uspto-grants-1982_08
Patentnummer
US04347386

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