Glycidyl methacrylate → HCID 86744516, Verbindung

HRID 704056Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 704056
[H-].[Na+].[C:3]([C:6]1[CH:19]=[CH:18][C:17]2[S:16][C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[NH:9][C:8]=2[CH:7]=1)(=[O:5])[CH3:4].[C:20]([O:25][CH2:26][CH:27]1[O:29][CH2:28]1)(=[O:24])[C:21]([CH3:23])=[CH2:22]>O1CCCC1>[C:20]([O:25][CH2:26][CH:27]([OH:29])[CH2:28][C:7]1[C:8]2[NH:9][C:10]3[C:15](=[CH:14][CH:13]=[CH:12][CH:11]=3)[S:16][C:17]=2[CH:18]=[CH:19][C:6]=1[C:3](=[O:5])[CH3:4])(=[O:24])[C:21]([CH3:23])=[CH2:22]

Komponenten

5

Edukt 3

HCID 7837Glycidyl methacrylateHCID 24758Sodium hydrideHCID 81131Methyl phenothiazin-2-yl ketone

Produkt 1

HCID 86744516HCID 86744516, VerbindungAusbeute 72,3 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel2×

Versuchsvorschrift

0.20 g (0.0086 mol) of sodium hydride was added carefully to a solution of 2-acetylphenothiazine (2 g, 0.0083 mol) in 150 ml tetrahydrofuran under agitation below 5° C. A solution of glycidyl methacrylate (1.88 g, 0.013 mol) in 10 ml tetrahydrofuran was added dropwise to above solution. The reaction was kept at room temperature for 48 hours. After the solvent was removed, the residue was washed with dilute HCl and water. Dried. 2.3 g of product was obtained by recrystallization with ethyl acetate.

Aufarbeitung

  1. customAfter the solvent was removed
  2. washthe residue was washed with dilute HCl and water
  3. customDried

Quellen und Nachweise

ORD-Eintrag
ord-baf805c5eeec4a2e9733b61eafdf5c87
Quelldatensatz
uspto-grants-1991_01
Patentnummer
US04985559

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