HCID 21884567, Verbindung → HCID 21884491, Verbindung
Reaktionsgleichung
[N+:1]([C:4]1[CH:5]=[CH:6][C:7]([O:25][CH2:26][C:27]2[CH:31]=[CH:30][O:29][CH:28]=2)=[C:8]([C:10]2[O:11][C:12]3[CH:18]=[CH:17][C:16]([C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:15][C:13]=3[N:14]=2)[CH:9]=1)([O-])=O>[Zn]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([O:25][CH2:26][C:27]2[CH:31]=[CH:30][O:29][CH:28]=2)=[C:8]([C:10]2[O:11][C:12]3[CH:18]=[CH:17][C:16]([C:19]4[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=4)=[CH:15][C:13]=3[N:14]=2)[CH:9]=1Komponenten
3
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
Prepared by the method of Example 47b), from 2-(5-nitro-2-(3-furanylmethoxy)phenyl)-5-phenylbenzoxazole (392 mg, 0.95 mmol) and zinc (622 mg, 9.5 mmol) the subtitle compound was obtained (382 mg, 93%). The product was used directly in the next step without purification.
Quellen und Nachweise
- ORD-Eintrag
- ord-ecbab0aacaa446dfa1338f3e92e1b89a
- Quelldatensatz
- uspto-grants-2006_11