Diglycolamine → N-(2-hydroxyethoxyethyl)hexahydrophthalimide

HRID 726483

Reaktionsgleichung

Reaktionsgleichung von HRID 726483
[NH2:1][CH2:2][CH2:3][O:4][CH2:5][CH2:6][OH:7].[C:8]1(=O)[O:13][C:11](=[O:12])[CH:10]2[CH2:14][CH2:15][CH2:16][CH2:17][CH:9]12>C(O)C>[OH:7][CH2:6][CH2:5][O:4][CH2:3][CH2:2][N:1]1[C:11](=[O:12])[CH:10]2[CH2:14][CH2:15][CH2:16][CH2:17][CH:9]2[C:8]1=[O:13]

Komponenten

4

Edukt 2

HCID 13578DiglycolamineHCID 85689Hexahydrophthalic anhydride

Produkt 1

HCID 55023972N-(2-hydroxyethoxyethyl)hexahydrophthalimideAusbeute 96 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A 500-ml, two necked flask was equipped with a magnetic stirring bar, heating mantle and condenser. The flask was charged with 51 g of 2-(aminoethoxy)ethanol (0.49 mol.) and 250 ml of ethanol. Next, 75 g of hexahydrophthalic anhydride (0.49 mol.) was slowly added to the flask. After the addition was complete the reaction was refluxed for 12 hours. The IR spectrum indicated the reaction was complete. The ethanol was removed with a rotoevaporator to yield 113 g (96%) of N-(2-hydroxyethoxyethyl)hexahydrophthalimide.

Aufarbeitung

  1. customA 500-ml, two necked flask was equipped with a magnetic stirring bar
  2. temperatureheating mantle and condenser
  3. additionAfter the addition
  4. temperaturewas refluxed for 12 hours
  5. customThe ethanol was removed with a rotoevaporator

Quellen und Nachweise

ORD-Eintrag
ord-55ac8588a3ab43d0ba645d1f0bf86fc2
Quelldatensatz
uspto-grants-1998_01
Patentnummer
US05709935

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