Ethanol → Butyric acid [1-(6-methyl-2,3-dihydro-2-pyranyl)ethylidene]hydrazide

HRID 728546

Reaktionsgleichung

Reaktionsgleichung von HRID 728546
[C:1]([CH:4]1[CH2:9][CH2:8][CH:7]=[C:6]([CH3:10])[O:5]1)(=O)[CH3:2].[C:11]([NH:16][NH2:17])(=[O:15])[CH2:12][CH2:13][CH3:14].C(O)C>O>[CH3:10][C:6]1[O:5][CH:4]([C:1](=[N:17][NH:16][C:11](=[O:15])[CH2:12][CH2:13][CH3:14])[CH3:2])[CH2:9][CH2:8][CH:7]=1

Komponenten

5

Edukt 3

HCID 702EthanolHCID 77079ButyrohydrazideHCID 141413Ethanone, 1-(3,4-dihydro-6-methyl-2H-pyran-2-yl)-

Produkt 1

HCID 131717001Butyric acid [1-(6-methyl-2,3-dihydro-2-pyranyl)ethylidene]hydrazideAusbeute 12 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

A mixture of 5.0 gm (0.0356 mole) of 2-acetyl-6-methyl-2,3-dihydropyran, 3.64 gm (0.0356 mole) of n-butyric acid hydrazide and 100 ml of ethanol is refluxed 24 hr. The mixture is diluted with water to the cloud point and chilled. The product is collected, washed with water and dried to give 0.93 gm (12%) of the title compound having a melting point of 72.8° C.

Aufarbeitung

  1. temperatureis refluxed 24 hr
  2. temperaturechilled
  3. customThe product is collected
  4. washwashed with water
  5. customdried

Quellen und Nachweise

ORD-Eintrag
ord-f5ee7a77cb3648eeaa26c629764f2bdb
Quelldatensatz
uspto-grants-1991_09
Patentnummer
US05049561

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