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Hydrochloric Acid → Ethylimidazolium phenol salt

HRID 76209
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 76209
[C:1]1([Si](OC)(OC)OC)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O:16][Si](O[CH2:25][CH3:26])(OCC)OCC)C.C[Si](OCC)(OCC)OCC.C(OCO[Si](CCC1C=CC=CC=1)(OC)OC)(C)(C)C.Cl.C(OCC(O)C)C.C([C:68]1[NH:69][CH:70]=[CH:71][N:72]=1)C>O.C(O)C.CC(C)=O>[C:1]1([OH:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:70]([N+:69]1[CH:26]=[CH:25][NH:72][CH:68]=1)[CH3:71]
KomponentenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

11

Edukt 7

HCID 313Hydrochloric Acid2×HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 661302-EthylimidazoleHCID 67001992
Tert-butoxyphenylethyltrimethoxysilane

Produkt 1

HCID 131731792Ethylimidazolium phenol salt

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 180AcetoneLösungsmittelHCID 702EthanolLösungsmittelHCID 962WaterLösungsmittel

Versuchsvorschrift

4.99 g of phenyltrimethoxysilane, 67.99 g of tetraethoxysilane, 26.90 g of methyltriethoxysilane, 0.17 g of tert-butoxyphenylethyltrimethoxysilane, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.07 g of a 0.01 M hydrochloric acid aqueous solution was added to the mixed solution. The reaction was carried out for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol, water and hydrochloric acid being reaction by-products were distilled off under reduced pressure to obtain a hydrolysis-condensation product. To the hydrolysis-condensation product, 0.05 g of ethylimidazole was added to obtain an ethylimidazolium phenol salt-containing Si polymer. The obtained polymer corresponded to a polymer having four types of unit structures of Formula (3-18). The molecular weight Mw of the obtained polymer measured by GPC was found to be 1,500 in terms of polystyrene.

Aufarbeitung

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customthe resultant reaction solution
  6. distillationwere distilled off under reduced pressure
  7. customto obtain a hydrolysis-condensation product

Quellen und Nachweise

ORD-Eintrag
ord-39ee17805ebf4d2798c4eb3fd69ec3c2
Quelldatensatz
uspto-grants-2014_09
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US08835093B2

Notizen zur Reaktion

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