Potassium Hydroxide → HCID 12474700, Verbindung

HRID 840084Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 840084
[CH2:1]([C:9]1[CH:10]([C:12]([O:14]CC)=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[K+]>CCOCC>[CH2:1]([C:9]1[CH:10]([C:12]([OH:14])=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Komponenten

4

Edukt 2

HCID 14797Potassium HydroxideHCID 22621698Ethyl 2-octylcycloprop-2-ene-1-carboxylate

Produkt 1

HCID 12474700HCID 12474700, VerbindungAusbeute 81,5 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

Ethyl 2-octylcycloprop-2-ene-1-carboxylate (1.12 g, 5 mmol) and 100 ml of 0.2 N potassium hydroxide were stirred at room temperature for one week. Ether was added and the phases were separated. The aqueous phase was acidified and extracted with methylene chloride. The organic phase was dried over magnesium sulfate and stripped to give 0.8 g of 2-octylcycloprop-2-ene-1-carboxylic acid.

Aufarbeitung

  1. customthe phases were separated
  2. extractionextracted with methylene chloride
  3. dry with materialThe organic phase was dried over magnesium sulfate

Quellen und Nachweise

ORD-Eintrag
ord-cf19c3b1ee5b4fdeb74266067d37b03a
Quelldatensatz
uspto-grants-2002_04
Patentnummer
US06365549B2

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