Phenyl Isothiocyanate → 5-(Benzylsulfanylmethyl)-3-phenyl-2-sulfanylideneimidazolidin-4-one

HRID 846640

Reaktionsgleichung

Reaktionsgleichung von HRID 846640
[CH2:1]([S:8][CH2:9][C@@H:10]([C:12]([OH:14])=O)[NH2:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[OH-].[Na+].[C:17]1([N:23]=[C:24]=[S:25])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[C:17]1([N:23]2[C:12](=[O:14])[CH:10]([CH2:9][S:8][CH2:1][C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[NH:11][C:24]2=[S:25])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Komponenten

4

Edukt 3

HCID 7673Phenyl IsothiocyanateHCID 14798Sodium HydroxideHCID 193613S-benzyl-L-cysteine

Produkt 1

HCID 28723155-(Benzylsulfanylmethyl)-3-phenyl-2-sulfanylideneimidazolidin-4-one

Versuchsvorschrift

When approximately equimolar amounts of S-benzylcysteine, sodium hydroxide, and phenylisothiocyanate was reacted according to the procedure described for the preparation of the compound of Example 2, the title compound herein was obtained.

Quellen und Nachweise

ORD-Eintrag
ord-cb4adb0fc1354ee7b5563db546de0263
Quelldatensatz
uspto-grants-1992_08
Patentnummer
US05137904

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