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Triphenylphosphine → (3r)-Thioacetic acid s-[3-[7-(cyclopropanecarbonyl-amino)-1-oxo-1,3-dihydro-isoindol-2-yl]-3-(3-ethoxy-4-methoxy-phenyl)-propyl] ester

HRID 853968
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Reaktionsgleichung

Reaktionsgleichung von HRID 853968
[CH2:1]([O:3][C:4]1[CH:5]=[C:6]([C@H:12]([N:16]2[C:24](=[O:25])[C:23]3[C:18](=[CH:19][CH:20]=[CH:21][C:22]=3[NH:26][C:27]([CH:29]3[CH2:31][CH2:30]3)=[O:28])[CH2:17]2)[CH2:13][CH2:14]O)[CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH3:2].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[C:51]([OH:54])(=[S:53])[CH3:52].CC(OC(/N=N/C(OC(C)C)=O)=O)C>C1COCC1.CO>[CH:29]1([C:27]([NH:26][C:22]2[CH:21]=[CH:20][CH:19]=[C:18]3[C:23]=2[C:24](=[O:25])[N:16]([C@@H:12]([C:6]2[CH:7]=[CH:8][C:9]([O:10][CH3:11])=[C:4]([O:3][CH2:1][CH3:2])[CH:5]=2)[CH2:13][CH2:14][S:53][C:51](=[O:54])[CH3:52])[CH2:17]3)=[O:28])[CH2:31][CH2:30]1
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Komponenten

7

Edukt 4

HCID 11776TriphenylphosphineHCID 5363146Diisopropyl azodicarboxylateHCID 9845251(1R)-cyclopropanecarboxylic acid {2-[1-(3-ethoxy-4-methoxy-phenyl)-3-hydroxy-propyl]-3-oxo-2,3-dihydro-1H-isoindol-4-yl}-amideHCID 178418634HCID 178418634, Verbindung

Produkt 1

HCID 87540694
(3r)-Thioacetic acid s-[3-[7-(cyclopropanecarbonyl-amino)-1-oxo-1,3-dihydro-isoindol-2-yl]-3-(3-ethoxy-4-methoxy-phenyl)-propyl] ester
Ausbeute 81,3 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 887MethanolLösungsmittelHCID 8028TetrahydrofuranLösungsmittel2×

Versuchsvorschrift

To a solution of (1R)-cyclopropanecarboxylic acid {2-[1-(3-ethoxy-4-methoxy-phenyl)-3-hydroxy-propyl]-3-oxo-2,3-dihydro-1H-isoindol-4-yl}-amide (5.7 g, 13 mmol), triphenyl phosphine (7.1 g, 2.4 mmol) and thioacetic acid (2.2 mL, 31 mmol) in THF (50 mL) was added a solution of DIAD (5.5 mL, 28 mmol) in THF (50 mL) at room temperature. After 4 hrs, methanol (5 mL) was added to the solution. The solvent was removed in vacuo. The residue was purified with Chromatography to give (3R)-thioacetic acid S-[3-[7-(cyclopropanecarbonyl-amino)-1-oxo-1,3-dihydro-isoindol-2-yl]-3-(3-ethoxy-4-methoxy-phenyl)-propyl] ester (5.1 g, 79% yield). To a solution of (3R)-thioacetic acid S-[3-[7-(cyclopropanecarbonyl-amino)-1-oxo-1,3-dihydro-isoindol-2-yl]-3-(3-ethoxy-4-methoxy-phenyl)-propyl] ester (5.0 g, 10 mmol) and methyl iodide (0.8 mL, 13 mmol) in methanol (40 mL) was added a solution of sodium hydroxide (5N, 4.2 mL, 21 mmol) at room temperature. After 2 hrs, to the mixture was added water (40 mL), methylene chloride (20 mL), and oxone (18 g, 29 mmol) and kept for 1.5 hrs. The mixture was extracted with methylene chloride (100 mL) and water (50 mL). The organic layer was washed with Na2S2O3 (10% 50 mL), brine (50 mL) and dried over MgSO4. The solvent was removed in vacuo. The residue was purified with chromatography (Silica Gel) to give (3R)-cyclopropanecarboxylic acid {2-[1-(3-ethoxy-4-methoxy-phenyl)-3-methanesulfinyl-propyl]-3-oxo-2,3-dihydro-1H-isoindol-4-yl}-amide as a white solid (320 mg, 6% yield): mp, 122-125° C.; 1H NMR (CDCl3) δ 0.86-0.93 (m, 2H, CH2), 1.08-1.14 (m, 2H, CH2), 1.45 (t, J=7 Hz, 3H, CH3), 1.63-1.72 (m, 1H, CH), 2.58 and 2.59 (2s, 3H, CH3), 2.60-2.82 (m, 4H, CH2CH2), 3.86 (s, 3H, CH3), 3.97 (d, J=17 Hz, 1H, NCHH), 4.06 (q, J=7 Hz, 2H, CH2), 4.31 and 4.35 (2 sets of d, J=17 Hz, 1H, NCHH), 5.50-5.59 (m, 1H, NCH), 6.84-7.02 (m, 4H, Ar), 7.41-7.48 (m, 1H, Ar), 8.43 (d, J=8 Hz, 1H, Ar), 10.54 (s, 1H, NH); 13C NMR (CDCl3) δ 8.28, 14.76, 16.18, 24.28, 24.76, 38.95, 45.71, 45.89, 51.22, 51.42, 53.07, 53.63, 55.99, 64.64, 111.54, 112.49, 116.89, 117.19, 117.80, 119.54, 130.38, 130.48, 133.37, 138.04, 141.36, 148.77, 149.40, 169.79, 169.82, 172.66; Anal Calcd for C25H30N2O5S+0.8H2O: C, 61.93; H, 6.57; N, 5.78; H2O, 2.97. Found: C, 61.63; H, 6.62; N, 5.61; H2O, 2.19.

Aufarbeitung

  1. customThe solvent was removed in vacuo
  2. customThe residue was purified with Chromatography

Quellen und Nachweise

ORD-Eintrag
ord-e82820eac86c48b3917477f69f40b4e5
Quelldatensatz
uspto-grants-2007_08
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US07256210B2

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