Dimethyl Sulfate → HCID 21867082, Verbindung

HRID 857127Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 857127
[I:1][C:2]1[CH:3]=[C:4]([N:8]2[CH2:12][C:11](=[O:13])[NH:10][C:9]2=[O:14])[CH:5]=[CH:6][CH:7]=1.[OH-].[K+].S(OC)(O[CH3:21])(=O)=O>O>[I:1][C:2]1[CH:3]=[C:4]([N:8]2[CH2:12][C:11](=[O:13])[N:10]([CH3:21])[C:9]2=[O:14])[CH:5]=[CH:6][CH:7]=1

Komponenten

5

Edukt 3

HCID 6497Dimethyl SulfateHCID 14797Potassium HydroxideHCID 218671771-(3-Iodophenyl)-2,4-imidazolidinedione

Produkt 1

HCID 21867082HCID 21867082, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

1-(3-Iodophenyl)imidazolidine-2,4-dione (0.588 g) was suspended in water (13 ml) and treated with potassium hydroxide (0.37 g). The reaction was placed in a warming bath (45° C.) and treated with dimethyl sulfate (0.784 ml). After stirring for 4 h the reaction mixture was chilled and filtered. The cake was washed with water and dried to give the title compound (0.381 g). LCMS RT=2.94 min.

Aufarbeitung

  1. customThe reaction was placed in a warming bath
  2. temperaturewas chilled
  3. filtrationfiltered
  4. washThe cake was washed with water
  5. customdried

Quellen und Nachweise

ORD-Eintrag
ord-4fbf68c3560c4f87bed139a7a511c906
Quelldatensatz
uspto-grants-2006_12
Patentnummer
US07144908B2

Notizen zur Reaktion

Wird geladen…