HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
4-Methylbenzenethiol → 1-[[(4-Methylphenyl)thio]methyl]-4-(trifluoromethoxy)benzene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 4-Methylbenzenethiol | HCID 7811 | — |
| Edukt | 4-(Trifluoromethoxy)benzyl Chloride | HCID 2777261 | — |
| Produkt | 1-[[(4-Methylphenyl)thio]methyl]-4-(trifluoromethoxy)benzene | HCID 10851611 | 80,1% |
Reaktionsschritte
The procedure of Example 87 is repeated using 11.8 g of p-thiocresol and 9.6 g of 4-(trifluoromethoxy)benzyl chloride. This affords 10.9 g of the desired product as white crystals. mp 74°-76° C. MS(CI): m/z 299(MH+). Calcd for C15H13F3OS: C=60.39, H=4.39, F=19.11, S=10.75 Found C=60.33, H=4.26, F=19.34, S=11.01
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05561141 |
| Quelldatensatz | uspto-grants-1996_10 |
| ORD ID | ord-98e1b32b22294ace80b4a3c5e59c50d2 |
| Quellennotiz | uspto-grants-1996_10 |