Pyridine → 8-Dodecen-1-ol, 1-acetate, (8Z)-

HRID 879042

Reaktionsgleichung

Reaktionsgleichung von HRID 879042
[CH:1](=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10]/[CH:11]=[CH:12]\CCCC.[CH3:18][C:19](OC(C)=O)=[O:20].N1C=CC=CC=1.C(O)CCCCCC/C=C\CCC>>[C:19]([O:17][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]/[CH:8]=[CH:9]\[CH2:10][CH2:11][CH3:12])(=[O:20])[CH3:18]

Komponenten

5

Edukt 4

HCID 1049PyridineHCID 7918Acetic AnhydrideHCID 52832958-Dodecen-1-ol, (8Z)-HCID 536449511-Hexadecenal, (11Z)-

Produkt 1

HCID 53633778-Dodecen-1-ol, 1-acetate, (8Z)-Ausbeute 90 %

Versuchsvorschrift

By acetylation of compound 2: According to the procedure for compound 6, Ac2O (0.29 mL, 3.0 mmol), pyridine (0.14 mL, 1.8 mmol), and alcohol 12 (0.28 g, 1.5 mmol) were reacted to provide 13 (19 g, 90% yield, 86% Z as determined by 1H-NMR) as a colorless oil.

Aufarbeitung

  1. customwere reacted

Quellen und Nachweise

ORD-Eintrag
ord-8d0a89f683b240769b5490826310d381
Quelldatensatz
uspto-grants-2015_03
Patentnummer
US08987531B2

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