Indium hydroxide → Indium(III) Bis-triflimide

HRID 890856Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 890856
[OH-].[In+3:2].[OH-].[OH-].[NH:5]([S:13]([C:16]([F:19])([F:18])[F:17])(=[O:15])=[O:14])[S:6]([C:9]([F:12])([F:11])[F:10])(=[O:8])=[O:7]>O>[NH:5]([S:6]([C:9]([F:12])([F:10])[F:11])(=[O:8])=[O:7])[S:13]([C:16]([F:19])([F:18])[F:17])(=[O:15])=[O:14].[NH:5]([S:6]([C:9]([F:12])([F:10])[F:11])(=[O:8])=[O:7])[S:13]([C:16]([F:19])([F:18])[F:17])(=[O:15])=[O:14].[In+3:2]

Komponenten

4

Edukt 2

HCID 88636Indium hydroxideHCID 157857Bis(trifluoromethane)sulfonimide

Produkt 1

HCID 131725280Indium(III) Bis-triflimide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

5.0 g of Indium (III) hydroxide was dissolved in 50 ml of water and to which 27.0 g of HNTf2 was added and stirred at room temperature for 24 hours. The reaction mixture was filtered and the filtrate was concentrated on a rotary evaporator and dried under vacuum (1 mmHg) for 3 days at 120° C. The unpurified indium(III) bis-triflimide was found to be an excellent Friedel-Crafts catalyst for the reaction of toluene, anisole and xylene with benzoyl chloride or benzoic anhydride.

Aufarbeitung

  1. additionwas added
  2. filtrationThe reaction mixture was filtered
  3. concentrationthe filtrate was concentrated on a rotary evaporator
  4. customdried under vacuum (1 mmHg) for 3 days at 120° C
  5. customfor the reaction of toluene, anisole and xylene with benzoyl chloride or benzoic anhydride

Quellen und Nachweise

ORD-Eintrag
ord-4978f419860c499cad161345f1240e86
Quelldatensatz
uspto-grants-2006_02
Patentnummer
US06998497B2

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