Reaktionsgleichung
[CH2:1]([SH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH2:12]([C:14]1OCC[N:18]=1)C.[ClH:19]>[Cl-].[Zn+2].[Cl-]>[ClH:19].[CH2:1]([S:11][CH2:12][CH2:14][NH2:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Reaktionsbedingungen
- Temperatur
- 140 °C
Versuchsvorschrift
Approximately 225 pounds of decylmercaptan are loaded into a jacketed reactor equipped with an agitator. 1.25 pounds of zinc chloride catalyst are added through the manhole. The system is heated to approximately 140° C. and 130 pounds of 2-ethyl-2-oxazoline are added at the rate of 3 lbs/min in about 45 minutes. About 30 minutes are allowed for the reaction to be completed, the reactor cooled to approximately 120° C. and 155 pounds of 32 weight percent hydrochloric acid are then added to the reaction mixture. The reactor is heated to 150°-160° C., at which time the vapor pressure of the system is approximately 60 psi. The temperature is maintained near 150° C. for 2 hours to complete the hydrolysis.
Aufarbeitung
- customequipped with an agitator
- customAbout 30 minutes are allowed for the reaction
- temperaturethe reactor cooled to approximately 120° C.
- temperatureThe reactor is heated to 150°-160° C., at which time the vapor pressure of the system
- temperatureThe temperature is maintained near 150° C. for 2 hours
- customthe hydrolysis
Quellen und Nachweise
- ORD-Eintrag
- ord-075d2c69bb764114b350892e90964ac0
- Quelldatensatz
- uspto-grants-1992_06
- Patentnummer
- US05118534
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