Trifluoroiodomethane → HCID 86743769, Verbindung

HRID 893257Notizen

Reaktionsgleichung

I[As:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[F:15][C:16]([F:19])([F:18])I>>[C:3]1([As:2]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:16]([F:19])([F:18])[F:15])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Komponenten

Edukt 2

HCID 16843Trifluoroiodomethane

HCID 238215Diphenylarsinous iodide

Produkt 1

HCID 86743769HCID 86743769, Verbindung

Versuchsvorschrift

R. Cullen in an article "Perfluoroalkyl Arsenicals, Part II The Preparation and Properties of Aryl Perfluoroalkyl Arsenicals", reported in Canadian Journal of Chemistry, Volume 38, 1960, pg. 445-451, describes the reaction of iododiphenylarsine with trifluoroiodomethane to produce diphenyltrifluoromethylarsine. Thermal decomposition of diphenyltrifluoromethylarsine resulted in undisclosed black solid deposit.

Quellen und Nachweise

ORD-Eintrag: ord-9673e52b583a4cb3860e0a609d18591e
Quelldatensatz: uspto-grants-1992_06
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05124278

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