Azide → 1-Amino-3-acetoxy acetone

HRID 903195

Reaktionsgleichung

Reaktionsgleichung von HRID 903195
[N:1]([CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6])=[N+]=[N-].[N-]=[N+]=[N-]>C(OC(=O)C)C.[Pd]>[NH2:1][CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6]

Komponenten

5

Edukt 2

HCID 33558AzideHCID 144347801-Azido-3-acetoxyacetone

Produkt 1

HCID 221655021-Amino-3-acetoxy acetone

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 8857Ethyl AcetateLösungsmittel

Versuchsvorschrift

1-Azido-3-acetoxyacetone (15.7 g.) is dissolved in ethylacetate (200 ml.). The 10% palladium on carbon catalyst (1.0 g.) is added; the mixture is reduced under hydrogen at atmospheric pressure until the infrared spectrum of an aliquot indicates the absence of the azide. The catalyst is filtered off and the filtrate is evaporated to afford 1-amino-3-acetoxy acetone.

Aufarbeitung

  1. filtrationThe catalyst is filtered off
  2. customthe filtrate is evaporated

Quellen und Nachweise

ORD-Eintrag
ord-44403b84da5b4bf499d6bc0f5f0501bb
Quelldatensatz
uspto-grants-1980_10
Patentnummer
US04226866

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