Methanethioic acid, O-ethyl ester → HCID 20528715, Verbindung

HRID 903865Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 903865
[N:1]([CH2:4][CH2:5][CH2:6][CH:7]1[CH2:12][CH2:11][CH2:10][CH2:9][NH:8]1)=[N+:2]=[N-:3].[CH:13](OCC)=[S:14]>CCOCC>[CH:13]([N:8]1[CH2:9][CH2:10][CH2:11][CH2:12][CH:7]1[CH2:6][CH2:5][CH2:4][N:1]=[N+:2]=[N-:3])=[S:14]

Komponenten

4

Edukt 2

HCID 11073343Methanethioic acid, O-ethyl esterHCID 20528703HCID 20528703, Verbindung

Produkt 1

HCID 20528715HCID 20528715, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

To a solution of 2-(3'-azidopropyl)-piperidine (1.8 g) in ether (10 ml) was added ethyl thioformate (1.5 ml). The solution was kept at 4° C. overnight and evaporated to leave an oil which was purified by chromatograpy on silica gel. The IR-spectrum (CHCl3) showed strong bands at 2950, 2100, 1485, 1445 and 1250 cm-1.

Aufarbeitung

  1. customevaporated
  2. customto leave an oil which
  3. customwas purified by chromatograpy on silica gel

Quellen und Nachweise

ORD-Eintrag
ord-f79529b3c31f44ec8e0d9c83218ccfc9
Quelldatensatz
uspto-grants-1980_10
Patentnummer
US04229443

Notizen zur Reaktion

Wird geladen…