Potassium Hydroxide → 1H-Perfluoropropane

HRID 916308Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 916308
ClCl.C(F)(C(F)(F)F)C(F)(F)F.Cl[C:14]([F:23])([F:22])[C:15]([F:21])([F:20])[C:16]([F:19])([F:18])[F:17].[OH-].[K+]>>[CH:14]([C:15]([C:16]([F:19])([F:18])[F:17])([F:21])[F:20])([F:23])[F:22]

Komponenten

5

Edukt 4

HCID 14797Potassium HydroxideHCID 24526ChlorineHCID 611131-ChloroheptafluoropropaneHCID 679401,1,1,2,3,3,3-Heptafluoropropane

Produkt 1

HCID 624421H-Perfluoropropane

Versuchsvorschrift

According to another embodiment of the present invention, a 34 cubic centimeter Inconel™ reactor tube is equipped with a ceramic fiber heater. The reactor is purged with nitrogen between 150° C. and 200° C. The reactor is connected to tubing providing chlorine and the hydrofluorocarbon heptafluoropropane (HFC-227). The flow of the chlorine and HFC-227 is controlled with gas flowmeters. Table 3 below indicates the suggested reaction parameters as well as the expected results. Fluoromonomer precursor chloroheptafluoropropane (CFC-217) exiting the reactor is first passed through a 10% (wt./wt.) KOH solution and then dried over CaSO4, before being captured for subsequent gas chromatography analysis.

Aufarbeitung

  1. customthe suggested reaction parameters as well as the
  2. customexpected results
  3. dry with materialdried over CaSO4

Quellen und Nachweise

ORD-Eintrag
ord-9b0369d22c614c4ea37d5c076dca2959
Quelldatensatz
uspto-grants-2007_09
Patentnummer
US07268261B2

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