HCID 12970067, Verbindung → 2,4-Dipropylresorcinol
Reaktionsgleichung
[CH2:1]([C:4]1[C:10]([OH:11])=[CH:9][CH:8]=[C:7]([CH2:12][CH:13]=[CH2:14])[C:5]=1[OH:6])[CH:2]=[CH2:3]>CO.[Pd]>[CH2:1]([C:4]1[C:5]([OH:6])=[C:7]([CH2:12][CH2:13][CH3:14])[CH:8]=[CH:9][C:10]=1[OH:11])[CH2:2][CH3:3]Komponenten
4
Reagenzien, Katalysatoren, Lösungsmittel 2
Versuchsvorschrift
The product 2,6-bis-allylresorcinol (33.5 gm) was dissolved in methanol and hydrogenated under H2 Pressure (initial pressure 45 psig) over 10% Pd on carbon (300 mg). The reaction mixture was filtered through celite and reduced i. vac. The crude oil was flushed through a short SiO2 gel column eluting with ethyl ether. The resulting oil was purified by crystallization from hexanes:ether.
Aufarbeitung
- filtrationThe reaction mixture was filtered through celite
- customThe crude oil was flushed through a short SiO2 gel column
- washeluting with ethyl ether
- customThe resulting oil was purified by crystallization from hexanes
Quellen und Nachweise
- ORD-Eintrag
- ord-2bfb2671409546e88e8771b6b2fea5b7
- Quelldatensatz
- uspto-grants-2006_08
- Patentnummer
- US07091230B2
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