Benzene → Cyclohexyl acetate

HRID 926969

Reaktionsgleichung

Reaktionsgleichung von HRID 926969
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(O)CCCCC1.[C:14]([O:17]CC)(=[O:16])[CH3:15]>[Ru]>[C:14]([O:17][CH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)(=[O:16])[CH3:15]

Komponenten

5

Edukt 3

HCID 241BenzeneHCID 7966CyclohexanolHCID 8857Ethyl Acetate2×

Produkt 1

HCID 12146Cyclohexyl acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 23950RutheniumKatalysator

Versuchsvorschrift

When a benzene solution containing 15 mmols of cyclohexanol, 5 mmols of ethyl acetate and 0.05 mmols of complex 1 was refluxed under argon atmosphere, GC analysis after 28 hrs showed that all of the ethyl acetate disappeared and cyclohexyl acetate was formed as a single product (Table 8, entry 1). 1H NMR and GC-MS of the isolated product were identical to cyclohexyl acetate prepared by refluxing neat acetic anhydride with cyclohexanol.

Aufarbeitung

  1. temperaturewas refluxed under argon atmosphere

Quellen und Nachweise

ORD-Eintrag
ord-94025d6f8b0e416db512913c31d4ab47
Quelldatensatz
uspto-grants-2016_03
Patentnummer
US09290441B2

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