Benzophenone → Methyl phenylglyoxalate

HRID 931878

Reaktionsgleichung

Reaktionsgleichung von HRID 931878
[C:1]([C:4]1[CH:9]=CC=C[CH:5]=1)(=[O:3])C.[C:10]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)(=[O:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[C:24](OO[C:34](=[O:41])[C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)(=O)C1C=CC=CC=1.ClC1C=CC2SC3C(=CC=CC=3)[C:46](=[O:57])C=2C=1.N(C1C=C(S(O)(=O)=O)C(C=CC2C(S(O)(=O)=O)=CC(N=[N+]=[N-])=CC=2)=CC=1)=[N+]=[N-].CCC1C=C2[C:94](C3C(SC2=C(CC)C=1)=CC=CC=3)=[O:95]>>[CH3:5][CH:4]([CH2:1][O:3][CH:18]([C:10]([C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)=[O:17])[C:23]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:24]=1)[CH3:9].[CH3:94][O:95][C:46]([C:34]([C:35]1[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=1)=[O:41])=[O:57]

Komponenten

8

Versuchsvorschrift

Examples of the photopolymerization initiator include acetophenone, benzophenone, benzyl dimethyl ketanol, benzoyl peroxide, 2-chlorothioxanthone, 1,3-bis(4′-azidobenzal)-2-propane, 1,3-bis(4′-azidobenzal)-2-propane-2′-sulfonic acid, and 4,4′-diazidostilbene-2,2′-disulfonic acid. Examples of commercially available photopolymerization initiators include “IRGACURE (trade mark)-184”, “IRGACURE (trade mark)-369”, “DAROCUR (trade mark)-1173”, and “Lucirin-TPO” produced by BASF Corporation, “KAYACURE (trade mark) DETX” and “KAYACURE (trade mark) OA” produced by NIPPON KAYAKU Co., Ltd., “VICURE 10” and “VICURE 55” produced by Stauffer Chemical Co., “TRIGONAL PI” produced by Akzo Chemicals B.V., “Sandorey 1000” produced by Sandoz, “DEAP” produced by Upjohn Co., Ltd., and “Biimidazole” produced by Kurogane Kasei Co., Ltd.

Aufarbeitung

  1. custom”, “DAROCUR (trade mark)-1173”, and “Lucirin-TPO” produced by BASF Corporation, “
  2. customproduced by NIPPON KAYAKU Co

Quellen und Nachweise

ORD-Eintrag
ord-0d46314896bb44eab27d36f1de9c8e9c
Quelldatensatz
uspto-grants-2016_03
Patentnummer
US09298033B2

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