Azobisisobutyronitrile → 2-(Toluene-4-sulfonyloxy)ethyl methacrylate 3-hydroxypropyl acrylate

HRID 968061Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 968061
[C:1]([O:6][CH2:7][CH2:8][O:9][S:10]([C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1)(=[O:12])=[O:11])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:20]([O:24][CH2:25][CH2:26][CH2:27][OH:28])(=[O:23])[CH:21]=[CH2:22].C(OC)(=O)C(C)=C.CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[C:1]([O:6][CH2:7][CH2:8][O:9][S:10]([C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][CH:14]=1)(=[O:11])=[O:12])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:20]([O:24][CH2:25][CH2:26][CH2:27][OH:28])(=[O:23])[CH:21]=[CH2:22]

Komponenten

6

Edukt 4

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 331012-Propenoic acid, 3-hydroxypropyl esterHCID 143442492-(Toluene-4-sulfonyloxy)ethyl methacrylate

Produkt 1

HCID 867598752-(Toluene-4-sulfonyloxy)ethyl methacrylate 3-hydroxypropyl acrylateAusbeute 65 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Reaktionsbedingungen

Temperatur
67.5 °C

Versuchsvorschrift

In a 500 ml round-bottom flask was placed 0.3 mole of 2-(toluene-4-sulfonyloxy)ethyl methacrylate, 0.33 mole of 3-hydroxypropyl acrylate, 0.3 mole of methyl methacrylate, 300 g of tetrahydrofuran (THF), and 0.1 g-3 g of AIBN. The reaction mixture was heated at 60-75° C. for 5-20 hours. The product was precipitated in ethyl ether or n-hexane, filtered and dried to provide poly [2-(toluene-4-sulfonyloxy)ethyl methacrylate/3-hydroxypropyl acrylate/-methyl methacrylate] represented by the following chemical formula 22, at a yield of 65-70%.

Aufarbeitung

  1. customIn a 500 ml round-bottom flask was placed
  2. customThe product was precipitated in ethyl ether
  3. filtrationn-hexane, filtered
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-ffa0fa13bf534f1c82928ff8b652445c
Quelldatensatz
uspto-grants-2005_10
Patentnummer
US06956091B2

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