Sodium Chloride → Trimethoxy(methoxymethyl)silane

HRID 9702

Reaktionsgleichung

Reaktionsgleichung von HRID 9702
[CH3:1][O-:2].[Na+].Cl[CH2:5][Si:6]([O:11][CH3:12])([O:9][CH3:10])[O:7][CH3:8].[SiH4].[Cl-].[Na+]>CO>[CH3:1][O:2][CH2:5][Si:6]([O:11][CH3:12])([O:9][CH3:10])[O:7][CH3:8]

Komponenten

6

Edukt 4

HCID 5234Sodium ChlorideHCID 22212Silane, chloromethyl-trimethoxy-HCID 23953SilaneHCID 10942334Sodium Methoxide

Produkt 1

HCID 31548Trimethoxy(methoxymethyl)silane

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

340 g (6.3 mol) of sodium methylate (95% strength) are dissolved in portions in 2.5 l of methanol in a laboratory reactor blanketed with nitrogen. During this procedure, the solution heats up to 65° C. Thereafter, 995 g (5.8 mol) of chloromethyltrimethoxysilane are added dropwise over 1.5 h and stirring is effected for a further 30 minutes at the boil. On addition of the silane, sodium chloride is precipitated spontaneously as the salt, but the suspension remains readily stirrable until the end of the metering. The precipitated sodium chloride is filtered off with suction and the methanol is removed under a partial vacuum at 40–50° C. The residue is purified by distillation (97–98° C. at 172 mbar).

Aufarbeitung

  1. customheats up to 65° C
  2. customis precipitated spontaneously as the salt
  3. filtrationThe precipitated sodium chloride is filtered off with suction
  4. customthe methanol is removed under a partial vacuum at 40–50° C
  5. distillationThe residue is purified by distillation (97–98° C. at 172 mbar)

Quellen und Nachweise

ORD-Eintrag
ord-8cda2c9114054d9c960cc6d973d5c6a6
Quelldatensatz
uspto-grants-2006_08
Patentnummer
US07091298B2

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