Sodium Iodide → Iodomethyl octyl carbonate

HRID 974767Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 974767
[C:1](=[O:14])([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[O:2][CH2:3]Cl.[I-:15].[Na+]>CC(C)=O>[C:1](=[O:14])([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[O:2][CH2:3][I:15]

Komponenten

4

Edukt 2

HCID 5238Sodium IodideHCID 19969190Chloromethyl octyl carbonate

Produkt 1

HCID 19969200Iodomethyl octyl carbonateAusbeute 72,6 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 180AcetoneLösungsmittel

Versuchsvorschrift

To a solution of chloromethyl octyl carbonate (1.14 g, 0.005 mol) in acetone (10 ml) was added sodium iodide (2.3 g, 0.015 mol). The mixture was stirred for 3 hours, concentrated invacuo, and dissolved in dichloromethane (50 ml). This solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride, dried (sodium sulfate) and concentrated invacuo to yield iodomethyl octyl carbonate (1.14 g).

Aufarbeitung

  1. concentrationconcentrated invacuo
  2. dissolutiondissolved in dichloromethane (50 ml)
  3. washThis solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride
  4. dry with materialdried (sodium sulfate)
  5. concentrationconcentrated invacuo

Quellen und Nachweise

ORD-Eintrag
ord-e50a6d5bfbaf43b69f4c60a775680c32
Quelldatensatz
uspto-grants-1997_03
Patentnummer
US05607691

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