p-nitrophenol sodium salt → Tri(4-nitrophenoxy)tri(phenoxy)cyclotriphosphazene

HRID 979437

Reaktionsgleichung

Reaktionsgleichung von HRID 979437
Cl[P:2]1([O:24][C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[N:7]=[P:6](Cl)([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[N:5]=[P:4](Cl)([O:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[N:3]=1.[N+:31]([C:34]1[CH:40]=[CH:39][C:37]([O-:38])=[CH:36][CH:35]=1)([O-:33])=[O:32].[Na+]>O1CCCC1>[N+:31]([C:28]1[CH:29]=[CH:30][C:25]([O:24][P:2]2([O:38][C:37]3[CH:39]=[CH:40][CH:34]=[CH:35][CH:36]=3)[N:7]=[P:6]([O:38][C:37]3[CH:39]=[CH:40][C:34]([N+:31]([O-:33])=[O:32])=[CH:35][CH:36]=3)([O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)[N:5]=[P:4]([O:38][C:37]3[CH:39]=[CH:40][C:34]([N+:31]([O-:33])=[O:32])=[CH:35][CH:36]=3)([O:16][C:17]3[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=3)[N:3]=2)=[CH:26][CH:27]=1)([O-:33])=[O:32]

Komponenten

4

Edukt 2

HCID 13214p-nitrophenol sodium saltHCID 23418754Trichlorotriphenoxycyclotriphosphazene

Produkt 1

HCID 14274513Tri(4-nitrophenoxy)tri(phenoxy)cyclotriphosphazene

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

This material is obtained as a white solid by the treatment of sodium and phenol with hexachlorocyclotriphosphazene at -78° C. to produce the trichlorotriphenoxycyclotriphosphazene, according to D. Dell et al., J. Chem. Soc., 4072 (1965), which is incorporated herein by reference. This material is further reacted with sodium 4-nitrophenoxide in refluxing tetrahydrofuran to give the title compound in good yield.

Quellen und Nachweise

ORD-Eintrag
ord-076b72045e604f3193e8079edc061026
Quelldatensatz
uspto-grants-1987_05
Patentnummer
US04668589

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