Basic information
- CAS
1484-50-0- Standard SMILES
O=C(c1ccccc1)C(Br)c1ccccc1- InChIKey
ZFFBIQMNKOJDJE-UHFFFAOYSA-N- Molecular formula
- C14H11BrO
- Average molar mass
- 275.14 g/mol
- Monoisotopic mass
- 273.99932707
Names & identifiers
- Preferred name
- 2-Bromo-1,2-diphenylethan-1-one
- IUPAC
- 2-bromo-1,2-diphenylethanone
- English name
- 2-Bromo-2-phenylacetophenone
- Molecular formula
- C14H11BrO
- Molecular weight
- 275.14
Names & synonyms
Desyl bromide2-Bromo-1,2-diphenylethanoneEthanone, 2-bromo-1,2-diphenyl-2-Bromo-1,2-diphenylethan-1-oneEINECS 216-057-1DTXSID308836812Bromo2phenylacetophenoneRefChem:465779Ethanone, 2bromo1,2diphenylDTXCID401023186216-057-12-Bromo-2-phenylacetophenone
Show more names
Desyl bromide 97%AKOS BBS-00000845α-BromodeoxybenzoinA-BROMODESOXY BENZOIN2-bromo-1,2-diphenyl-ethanonPhenyl(α-bromobenzyl) ketone
1484-50-0MFCD000001362-bromo-1,2-diphenyl-ethanonealpha-BromodeoxybenzoindesylbromideDesyl bromide, 97%alpha-bromodesoxibenzoineSCHEMBL627867
Database identifiers
- CAS
1484-50-0- PubChem CID
- 102630
- DTXSID
DTXSID30883681- EC Number
- 216-057-1
- Nikkaji
- J206.691B
Properties
Computed structural properties
- XLogP
- 3.6
- Topological polar surface area
- 17.1 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 3
- Heavy atoms
- 16
- Formal charge
- 0
- Complexity
- 227
Experimental & physicochemical properties
Chemical ClassesOther Classes -> Aromatic Ketones, Halogenated
Physical DescriptionOff-white powder; [Sigma-Aldrich MSDS]
Physicochemical properties
- Melting point
- 56 · 56-58 °C (lit.)
- Boiling point
- 344.8 · 344.8±22.0 °C(Predicted)
- Density
- 1.393 · 1.3930 (rough estimate)
- refractive index
- 1.513 · 1.5130 (estimate)
- storage temp.
- 0 · 0-6°C
- solubility
- soluble in Toluene
- form
- Crystalline Powder
- color
- Beige-brown
- InChI
- 1S/C14H11BrO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13H
- InChIKey
- ZFFBIQMNKOJDJE-UHFFFAOYSA-N
- SMILES
- BrC(c1ccccc1)C(=O)c2ccccc2
Safety & regulation
Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.
GHS classification
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]
Hazard Classes and CategoriesSkin Corr. 1B (100%)
Toxicology
Adverse EffectsDermatotoxin - Skin burns.
Safety data
- PPE
- Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- 1759
- hs_code
- 29147000
- risk_code
- 34-36/37
- Signal word
- Danger
- Symbol(GHS)
- GHS05,GHS07
- hazard_code
- C
Chemistry & industry
Uses & manufacturing
General Manufacturing InformationEthanone, 2-bromo-1,2-diphenyl-: INACTIVE
Applications
UsesDesyl bromide has been used in:synthesis of phosphate esters of benzoin and benzoinyl N-carbobenzyloxyglycylphenylalanatenovel chemiluminogenic reaction for the sensitive determination of Arg-containing peptides
General DescriptionReaction of cesium N-carbobenzyloxyglycylphenylalanate with desyl bromide in DMF has been investigated.
Upstream & downstream products
Downstream products
Suppliers67 total
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海衡新化工科技有限公司13917104483; 13917104483 · [email protected]
Changzhou Anxuan Chemical Co., Ltd+86-0519-89882563 +86-18961279162 · [email protected]
河南赢创生物科技有限公司16650615803 · [email protected]
Related reactions
24 records
Compound notes
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